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Superconductivity at 12 K in La2IOs2: A 5d metal with osmium honeycomb layer

Hajime Ishikawa, Takeshi Yajima, Daisuke Nishio-Hamane, Shusaku Imajo, Koichi Kindo, Mitsuaki Kawamura

DOI 10.1103/PhysRevMaterials.7.054804 · Physical Review Materials

T1

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Abstract

We discovered superconductivity at Tc = 12 K in a layered compound La2IOs2 with an osmium honeycomb network. Despite heavy constituent elements unfavorable for a phonon mediated mechanism, Tc is the highest among lanthanoid iodides made of lighter elements such as La2IRu2 with Tc = 4.8 K. Electronic anomalies are observed below 60 K similar to those observed in La2IRu2 below 140 K. La2IOs2 is a layered 5d electron system providing a platform to investigate the interplay between the electronic anomaly, superconductivity, and strong magnetic field.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La2IOs2

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12Pressure not reportedonset
La2IOs2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

12Pressure not reportedonset
La2IOs2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

12Pressure not reportedonset
La2IRu2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

4.8Pressure not reportedunknown

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