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Decoupling of lattice and orbital degrees of freedom in an iron-pnictide superconductor

C. E. Matt, O. Ivashko, M. Horio, J. Choi, Q. Wang, D. Sutter, N. Dennler, M. H. Fischer, S. Katrych, L. Forro, J. Ma, B. Fu, B. Q. Lv, M. v. Zimmermann, T. K. Kim, N. C. Plumb, N. Xu, M. Shi, J. Chang

DOI 10.1103/PhysRevResearch.3.023220 · Physical Review Research

T1

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Abstract

The interplay between structural and electronic phases in iron-based superconductors is a central theme in the search for the superconducting pairing mechanism. While electronic nematicity is competing with superconductivity, the effect of purely structural orthorhombic order is unexplored. Here, using x-ray diffraction and angle-resolved photoemission spectroscopy, we reveal a structural orthorhombic phase in the electron-doped iron-pnictide superconductor Pr4Fe2As2Te0.88O4 (Tc=25 K), which is distinct from orthorhombicity in the nematic phase in underdoped pnictides. Despite the high electron doping we find an exceptionally high orthorhombic onset temperature (Tort∼250 K), no signatures of phase competition with superconductivity, and absence of electronic nematic order as the driving mechanism for orthorhombicity. Combined, our results establish a high-temperature phase in the phase diagram of iron-pnictide superconductors and impose strong constraints for the modeling of their superconducting pairing mechanism.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Pr4Fe2As2Te0.88O4

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25Pressure not reportedonset
Pr4Fe2As2Te0.88O4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

25Pressure not reportedonset
Ba(Fe1-xCox)2As2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

25Pressure not reportedunknown

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