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General Framework Enabling Polarity-Tunable Time-Reversal Symmetric Superconducting Diode Effects in Gate-Defined Homojunctions

Hongwei Zhang, Chunsheng Wang, Ran Wang, Senyang Pan, Hengning Wang, Jiaqiang Cai, Yonglai Liu, Zhe Qu, Xiangde Zhu, Wei Ning, Chuanying Xi, Jinglei Zhang, Ning Hao, Guolin Zheng, Mingliang Tian

DOI 10.1103/wm2k-vlvc · Physical Review X

T1

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Abstract

Symmetry breaking underlies various nonreciprocal transport phenomena. A well-known example is the semiconductor p−n junction diode, a cornerstone of modern electronics. Its superconducting counterpart—the superconducting diode effect (SDE)—has recently attracted intense interest due to its potential in ultra-low-power superconducting circuits. While most SDEs reported so far involve either explicit or spontaneous breaking of time-reversal symmetry (TRS), a comprehensive theoretical framework remains elusive. Moreover, a general mechanism enabling TRS-preserving SDEs with minimal dependence on material or device architecture has yet to be established. Here, we report polarity-tunable SDEs without breaking TRS, realized in superconducting n−n, p−n, and p−p homojunctions defined via local protonic gates in multilayer NbSe2. The local gates induce partial proton intercalation, generating a built-in proton concentration gradient across the transition zone between the gated and ungated regions—closely resembling the depletion layer in conventional semiconductor diodes. We find that the observed SDE arises from electric-field-driven variation of the proton concentration gradient in the transition region, which asymmetrically modulates the critical current: suppressing it in one direction and enhancing it in the other. This local-gate-driven, TRS-preserving mechanism offers a general and scalable strategy for realizing nonreciprocal superconducting transport. Our findings establish a material-agnostic platform for SDEs, broadly applicable across two-dimensional (2D) superconductors.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
NbSe2

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6.9Pressure not reportedonset

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