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Time-reversal symmetry breaking superconductivity in CaSb2

M. Oudah, Y. Cai, M. V. De Toro Sanchez, J. Bannies, M. C. Aronson, K. M. Kojima, D. A. Bonn

DOI 10.1103/PhysRevB.110.134524 · Physical Review B

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Abstract

CaSb2 is a bulk superconductor and a topological semimetal, making it a great platform for realizing topological superconductivity. In this work, we investigate the superconducting upper and lower critical field anisotropies using magnetic susceptibility and study the superconducting state using muon spin relaxation. The temperature dependence of the transverse-field relaxation rate can be fitted with a single-gap model or two-gap model. Zero-field relaxation shows little temperature dependence when the muon spin is parallel to the c* axis, while an increase in relaxation appears below 1 K when the muon spin is parallel to the ab plane. We conclude an s+is order parameter considering the breaking of time-reversal symmetry (TRS), which originates from competing interband interactions between the three bands of CaSb2. To explain the direction-dependent breaking of TRS we suggest loop currents developing in the plane of a distorted square net of Sb atoms.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
CaSb2

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1.6Pressure not reportedunknown
CaSb2

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1.6Pressure not reportedunknown
UPt3

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—Pressure not reportedunknown
Sr2RuO4

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—Pressure not reportedunknown
LaNiC2

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—Pressure not reportedunknown
Re6Zr

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—Pressure not reportedunknown
La7Ir3

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—Pressure not reportedunknown
FeSe

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—Pressure not reportedunknown
Ba1-xKxFe2As2

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—Pressure not reportedunknown
SrPtAs

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—Pressure not reportedunknown
CaPtAs

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—Pressure not reportedunknown
PrOs4Sb12

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—Pressure not reportedunknown
Bi2Se3

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—Pressure not reportedunknown

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