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Influence of magnetic rare-earth ion substitution on the magnetic susceptibility of high-Tc superconductors

F. Zuo, B. R. Patton, D. L. Cox, S. I. Lee, Y. Song, J. P. Golben, X. D. Chen, S. Y. Lee, Y. Cao, Y. Lu, J. R. Gaines, J. C. Garland, A. J. Epstein

DOI 10.1103/PhysRevB.36.3603 · Physical Review B

T1

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Abstract

We report detailed magnetic-susceptibility studies for the oxygen-deficient perovskite superconductors MBa2Cu3O7−δ (M=Y,Gd,Er,Ho). Normal-state behavior above Tc shows weak ferromagnetic (antiferromagnetic) tendencies for M=Y,Gd (M=Er,Ho), with 87% of the free-ion moment for M=Gd,Er,Ho. The estimated Fermi-level density of states is 6.4 states/eV Cu for M=Y,Gd, which is twice the band-structure estimate. The superconducting state shows a 20% or more flux exclusion at small field. The Curie contributions for M=Gd,Er,Ho are weakened for T<Tc due to diamagnetic screening. The local moments appear to have little or no effect on the superconducting state. These effects are well described by a simple theoretical model.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O7-δ

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90Pressure not reportedunknown
GdBa2Cu3O7-δ

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90Pressure not reportedunknown
ErBa2Cu3O7-δ

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90Pressure not reportedunknown
HoBa2Cu3O7-δ

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90Pressure not reportedunknown

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