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High-resolution heat capacity of YBa2Cu3O6.9 over the superconducting transition region

Richard A. Butera

DOI 10.1103/PhysRevB.37.5909 · Physical Review B

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Abstract

High-resolution heat-capacity data have been determined for a single-phase sample of YBa2Cu3O6.9 over the temperature range 77–150 K. Two anomalies were found: a λ-type transition occurring at 86.65 K and a discontinuity accompanied by a first-order transition occurring at 90.30 K. The discontinuity has a value of ΔCp/T=62 mJ (mol f.u.)−1 K−2, where f.u. denotes formula unit. An estimation of the latent heat and entropy associated with the first-order transition is given. The anomalies in the heat capacity are related to the changes in the resistance and Meissner effect and a mixed superconducting-normal state is proposed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O6.9

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90.3Pressure not reportedonset
YBa2Cu3O6.9

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

86.65Pressure not reportedzero_resistance
YBa2Cu3O6.9

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

86.65Pressure not reportedmidpoint

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