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Symmetry of holes in high-Tc superconductors

N. Nücker, H. Romberg, X. X. Xi, J. Fink, B. Gegenheimer, Z. X. Zhao

DOI 10.1103/PhysRevB.39.6619 · Physical Review B

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Abstract

High-energy electron energy-loss spectroscopy in transmission has been used to obtain information on the symmetry of unoccupied electronic states in the new high-Tc superconductors. In particular, for YBa2Cu3O7 and Bi2Sr2CaCu2O8, the O 1s and Cu 2p absorption edges have been measured for momentum transfer parallel and perpendicular to the a,b plane. Both σ and in-plane π holes on O, formed upon doping, are compatible with our experimental results. For YBa2Cu3O7, in both cases, holes must be in the planes and in the ribbons. Out-of-plane π holes can be excluded for YBa2Cu3O7 and Bi2Sr2CaCu2O8. In the undoped and doped compounds, the unoccupied states on the Cu sites have & symmetry. There is an admixture of about 10% of lower-lying states probably with & symmetry.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
YBa2Cu3O7

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90Pressure not reportedunknown
Bi2Sr2CaCu2O8

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

83Pressure not reportedunknown

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