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Optical properties of superconducting K3C60 and insulating K6C60

Yong-Nian Xu, Ming-Zhu Huang, W. Y. Ching

DOI 10.1103/PhysRevB.44.13171 · Physical Review B

T1

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Abstract

The electronic structures and the linear optical properties of superconducting fcc K3C60 and insulating bcc K6C60 are calculated by means of a first-principles method within the local-density approximation. The calculated optical properties for these two crystals as well as those of fcc C60 are in very good agreement with recent electron-energy-loss spectra measurements.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
K3C60

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—Pressure not reportedunknown
CsRbyC60

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33Pressure not reportedonset

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