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Specific heat and magnetic susceptibility of superconducting and semiconducting Nd1.85Ce0.15CuO4−δ

S. J. Collocott, R. Driver, C. Andrikidis

DOI 10.1103/PhysRevB.45.945 · Physical Review B

T1

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Abstract

Specific-heat (Cp) data in the range of 0.4–20 K for a polycrystalline specimen of Nd1.85Ce0.15CuO4−δ, in the superconducting state (δ=0.02) and on the same specimen, after annealing in air, in the semiconducting state (δ=0.0), are reported. Below 10 K, Cp in Nd1.85Ce0.15CuO4−δ, for both δ=0.02 and 0.0, is dominated by a Schottky anomaly. The Schottky anomaly has an entropy S within 5% of the R ln3 value. Limiting values for the Debye temperature, FTHETAD0 of 409±20 and 445±20 K are obtained in Nd1.85Ce0.15CuO4−δ for δ=0.02 and 0.0, respectively. Magnetic-susceptibility (κ) data in the range 2–280 K show that superconducting Nd1.85Ce0.15CuO4−δ, undergoes a superconducting transition at 22 K. Above 40 K, κ in Nd1.85Ce0.15CuO4−δ, for both δ=0.02 and 0.0, exhibits Curie-Weiss behavior, which is consistent with a material that displays antiferromagnetic coupling.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Nd1.85Ce0.15CuO4-δ

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24.3Pressure not reportedonset
Nd1.85Ce0.15CuO4-δ

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22Pressure not reportedmidpoint
Nd1.85Ce0.15CuO4-δ

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22Pressure not reportedunknown
La2-xSrxCuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
YBa2Cu3O7-δ

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—Pressure not reportedunknown
Bi2Sr2Can-1CunO2n+4

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—Pressure not reportedunknown
Tl2Ba2Can-1CunO2n+4

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—Pressure not reportedunknown

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