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Absence of an energy gap in measurements of Cu-O superconductors with high-resolution electron-energy-loss spectroscopy

R. B. Phelps, P. Akavoor, L. L. Kesmodel, A. L. Barr, J. T. Markert, J. Ma, R. J. Kelley, M. Onellion

DOI 10.1103/PhysRevB.50.6526 · Physical Review B

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Abstract

We report extensive measurements of Bi2Sr2CaCu2O8 (Bi 2:2:1:2) and YBa2Cu3O7 (Y 1:2:3) single crystals with high-resolution electron-energy-loss spectroscopy (HREELS). Both as-grown and oxygen-annealed Bi 2:2:1:2 samples were studied. In all cases, peaks due to surface optical phonons were observed at loss energies from 24 to 80 meV. We see no evidence for the weak feature near 60 meV which has been previously reported and attributed to the superconducting energy gap. Our results demonstrate that the optical conductivity of high-temperature superconductors deduced from HREELS, like that deduced from infrared spectroscopy, does not exhibit the gaplike structure expected for a BCS superconductor.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Bi2Sr2CaCu2O8

Archive — visibility unverified

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83Pressure not reportedonset
YBa2Cu3O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

92Pressure not reportedonset

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