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Specific heat and critical fields of the organic superconductor β″−(BEDT−TTF)2SF5CH2CF2SO3

S. Wanka, J. Hagel, D. Beckmann, J. Wosnitza, J. A. Schlueter, J. M. Williams, P. G. Nixon, R. W. Winter, G. L. Gard

DOI 10.1103/PhysRevB.57.3084 · Physical Review B

T1

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Abstract

We report on specific-heat, magnetization, and ac-susceptibility measurements of β″−(BEDT−TTF)2SF5CH2CF2SO3, an organic superconductor with Tc=4.5 K, where BEDT-TTF stands for bis(ethylenedithio)-tetrathiafulvalene. The jump of the specific heat C at Tc and the exact form of the specific-heat difference between C in the superconducting (B=0 T) and in the normal (B=3.5 T) state can be well described by BCS theory with strong coupling. We estimate an electron-phonon coupling parameter λ≈1.1. From measurements of C in magnetic fields we extract the upper critical field Bc2(T). Low-field dc-magnetization measurements were used to determine the temperature dependence of the lower critical field Bc1. From Tc down to ∼3 K the characteristic suppression of Bc1⊥(T) below the sensitivity limit is observed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
(BEDT-TTF)2SF5CH2CF2SO3

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4.5Pressure unresolvedunknown
(BEDT-TTF)2SF5CH2CF2SO3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

5.2Pressure unresolvedonset
(BEDT-TTF)2Cu(NCS)2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
(BEDT-TTF)2Cu(N(CN)2)Br

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
(BEDT-TTF)2Cu(N(CN)2)Cl

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

130.03 GPaunknown

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