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Organic superconductor with an incommensurate anion structure: (MDT−TSF)(AuI2)0.44

Tadashi Kawamoto, Takehiko Mori, Kazuo Takimiya, Yoshiro Kataoka, Yoshio Aso, Tetsuo Otsubo

DOI 10.1103/PhysRevB.65.140508 · Physical Review B

T1

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Abstract

The degree of charge transfer and the upper critical field of the organic superconductor (MDT−TSF)(AuI2)x have been investigated (MDT-TSF: methylenedithio-tetraselenafulvalene). The x-ray oscillation photograph indicates that the anion lattice is incommensurate with the donor lattice, and the chemical composition is (MDT−TSF)(AuI2)0.44. The charge-transfer degree of this salt is 0.44. The electrical resistivity and the Seebeck coefficient indicate that this salt is a good Fermi liquid above the superconducting transition temperature. The upper critical fields show anisotropic three-dimensional character in spite of the complicated incommensurate structure, and are within the Clogston-Chandrasekhar paramagnetic limit in all directions.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
(MDT-TSF)(AuI2)0.44

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5.1Pressure unresolvedonset
(MDT-TSF)(AuI2)0.44

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4.5Pressure unresolvedmidpoint
(MDT-TSF)(AuI2)0.44

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4.5Pressure unresolvedmidpoint
(TMTSF)2PF6

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—Pressure not reportedunknown
(BEDT-TTF)4Hg3Cl8

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—Pressure not reportedunknown
(BEDT-TTF)4Hg3Br8

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—Pressure not reportedunknown
(MDT-TTF)2AuI2

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—Pressure not reportedunknown
(TMTSF)2ClO4

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—Pressure not reportedunknown

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