Disordered polyhalide anion effect on the Fermi surface of the incommensurate organic superconductor (MDT-TSF)I0.77Br0.52
Tadashi Kawamoto, Takehiko Mori, Kengo Enomoto, Takako Konoike, Taichi Terashima, Shinya Uji, Hiroshi Kitagawa, Kazuo Takimiya, Tetsuo Otsubo
DOI 10.1103/PhysRevB.84.094518 · Physical Review B
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Abstract
The effect of disorder in polyhalide anions is investigated in terms of the degree of charge transfer and the Fermi surface in the incommensurate organic superconductor (MDT-TSF)I0.77Br0.52, where MDT-TSF is methylenedithio-tetraselenafulvalene. The Raman spectra suggest that the infinite polyhalide chains include the asymmetric trihalide anion I2Br− and that the degree of charge transfer from the donor molecule to the anion is 0.429, estimated from the lattice constants. The Shubnikov–de Haas (SdH) oscillation is in good agreement with this charge transfer degree. The beating behavior of the SdH oscillation gives a large interlayer transfer integral, which is consistent with a corrugated conducting sheet structure. The randomness of the disordered anions reduces the periodicity of the incommensurate anion potential; this destroys the Fermi surface reconstruction by the incommensurate anion potential. The factor dominating the superconducting transition temperature is not the randomness of the polyhalide anions but the effective cyclotron mass enhancement, i.e., the many-body effect.
Source-reported materials — not catalogue approval
| Formula | Reported Tc (K) | Pressure (GPa) | Type |
|---|---|---|---|
| (MDT-TSF)I0.77Br0.52 Archive — visibility unverified Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula. | 4 | Pressure unresolved | unknown |
| (MDT-TSF)(AuI2)0.436 Archive — visibility unverified Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula. | — | Pressure not reported | unknown |
| (MDT-TSF)(I3)0.422 Archive — visibility unverified Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula. | — | Pressure unresolved | unknown |
| κ-(ET)4Hg2.89Br8 Archive — visibility unverified Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula. | — | Pressure unresolved | unknown |
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