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Angle-resolved photoemission study of the quasi-one-dimensional superconductor β−Na0.33V2O5

K. Okazaki, A. Fujimori, T. Yamauchi, Y. Ueda

DOI 10.1103/PhysRevB.69.140506 · Physical Review B

T1

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Abstract

We have studied the electronic structure of β−Na0.33V2O5, which becomes a superconductor under pressure, by angle-resolved photoemission spectroscopy. Clear band dispersions are observed only along the chain direction, indicating the quasi-one-dimensional (1D) electronic structure. The spectra of the V 3d band are dominated by a Gaussian-like broad feature at ∼1eV below the Fermi level (EF) with negligible intensity at EF, which we attribute to strong electron-phonon coupling as in other 1D polaronic metals. In the momentum space, the spectra show a maximum intensity at k∼±π/4b, where b is the V-V distance along the b axis, reflecting the band filling of the chain and/or ladder.

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FormulaReported Tc (K)Pressure (GPa)Type
Na0.33V2O5

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88 GPaunknown

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