← Back to search

LiFeAs: An intrinsic FeAs-based superconductor with Tc=18 K

Joshua H. Tapp, Zhongjia Tang, Bing Lv, Kalyan Sasmal, Bernd Lorenz, Paul C. W. Chu, Arnold M. Guloy

DOI 10.1103/PhysRevB.78.060505 · Physical Review B

T1

Active bibliographic source — not scientific approval

Bibliographic access preserves source history; it does not approve extracted materials or validate reported claims. Review warnings on each occurrence separately.

Abstract

The synthesis and properties of LiFeAs, a high-Tc Fe-based superconducting stoichiometric compound, are reported. Single crystal x-ray studies reveal that it crystallizes in the tetragonal PbFCl type (P4/nmm) with a=3.7914(7) Å and c=6.364(2) Å. Unlike the known isoelectronic undoped intrinsic FeAs compounds, LiFeAs does not show any spin-density wave behavior but exhibits superconductivity at ambient pressures without chemical doping. It exhibits a respectable transition temperature of Tc=18 K with electronlike carriers and a very high critical field, Hc2(0)>80 T. LiFeAs appears to be the chemical equivalent of the infinite layered compound of the high-Tc cuprates.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
LiFeAs

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

18Pressure unresolvedonset
LiFeAs

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

18Pressure unresolvedonset
KFe2As2

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

3.8Pressure not reportedunknown
CsFe2As2

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

2.6Pressure not reportedunknown

Similar papers