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Roles of spin fluctuation and frustration in the superconductivity of β−(BDA-TTP)2X (X=SbF6,AsF6) under uniaxial compression

Hiroshi Ito, Tetsuo Ishihara, Hisaaki Tanaka, Shin-ichi Kuroda, Takeo Suzuki, Seiichiro Onari, Yukio Tanaka, Jun-ichi Yamada, Koichi Kikuchi

DOI 10.1103/PhysRevB.78.172506 · Physical Review B

T1

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Abstract

β-type BDA-TTP [BDA-TTP=2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene] salts possess high transition temperatures TC reaching 7 K among organic superconductors. TC of β−(BDA-TTP)2X (X=SbF6,AsF6) is studied by resistive measurements under uniaxial compression. TC once increases and takes a maximum under compression parallel to the donor stack while it decreases under compression perpendicular to the donor stack. These results are in agreement with the half-filled Hubbard model on the triangular lattice in which the compression controls the spin fluctuation and frustration in the weak pressure region.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
(BDA-TTP)2SbF6

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

7.5Pressure not reportedmidpoint
(BDA-TTP)2AsF6

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

6.9Pressure not reportedmidpoint
(BEDT-TTF)2ICl2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

14.28.2 GPaunknown

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