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Pressure-driven superconductivity in the transition-metal pentatelluride HfTe5

Yanpeng Qi, Wujun Shi, Pavel G. Naumov, Nitesh Kumar, Walter Schnelle, Oleg Barkalov, Chandra Shekhar, Horst Borrmann, Claudia Felser, Binghai Yan, Sergey A. Medvedev

DOI 10.1103/PhysRevB.94.054517 · Physical Review B

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Abstract

The discovery of superconductivity in hafnium pentatelluride HfTe5 under high pressure is reported. Two structural phase transitions and metallization with superconductivity developing at around 5 GPa are observed. A maximal critical temperature of 4.8 K is attained at a pressure of 20 GPa, and superconductivity persists up to the maximum pressure of the study (42 GPa). The combination of electrical transport and crystal structure measurements as well as theoretical electronic structure calculations enables the construction of a phase diagram of HfTe5 under high pressure.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
HfTe5

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1.85 GPaonset
HfTe5

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4.820 GPaonset
ZrTe5

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—Pressure not reportedunknown
ZrTe3

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—Pressure not reportedunknown

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