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Pressure effect and superconductivity in the β−Bi4I4 topological insulator

A. Pisoni, R. Gaál, A. Zeugner, V. Falkowski, A. Isaeva, H. Huppertz, G. Autès, O. V. Yazyev, L. Forró

DOI 10.1103/PhysRevB.95.235149 · Physical Review B

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Abstract

We report a detailed study of the transport properties of a β−Bi4I4 quasi-one-dimensional topological insulator. Electrical resistivity, thermoelectric power, thermal conductivity, and Hall coefficient measurements are consistent with the possible appearance of a charge-density-wave order at low temperatures. Both electrons and holes contribute to the conduction in β−Bi4I4 and the dominant type of charge carrier changes with temperature as a consequence of temperature-dependent carrier densities and mobilities. Measurements of resistivity and Seebeck coefficient under hydrostatic pressure up to 2 GPa show a shift of the charge-density-wave order to higher temperatures suggesting a strongly one-dimensional character at ambient pressure. Surprisingly, superconductivity is induced in β−Bi4I4 above 10 GPa with Tc of 4.0 K which is slightly decreasing upon increasing the pressure up to 20 GPa. Chemical characterization of the pressure-treated samples shows amorphization of β−Bi4I4 under pressure and rules out decomposition into Bi and BiI3 at room-temperature conditions.

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FormulaReported Tc (K)Pressure (GPa)Type
Bi4I4

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410 GPaunknown

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