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Why Does Undoped FeSe Become a High-Tc Superconductor under Pressure?

T. Imai, K. Ahilan, F. L. Ning, T. M. McQueen, R. J. Cava

DOI 10.1103/PhysRevLett.102.177005 · Physical Review Letters

T1

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Abstract

Unlike the parent phases of the iron-arsenide high-Tc superconductors, undoped FeSe is not magnetically ordered and exhibits superconductivity with Tc∼9 K. Equally surprising is the fact that applied pressure dramatically enhances the modest Tc to ∼37 K. We investigate the electronic properties of FeSe using Se77 NMR to search for the key to the superconducting mechanism. We demonstrate that the electronic properties of FeSe are very similar to those of electron-doped FeAs superconductors, and that antiferromagnetic spin fluctuations are strongly enhanced near Tc. Furthermore, applied pressure enhances spin fluctuations. Our findings suggest a link between spin fluctuations and the superconducting mechanism in FeSe.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
FeSe

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9Pressure unresolvedonset
FeSe

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140.7 GPaonset
FeSe

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161.4 GPaonset
FeSe

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222.2 GPaonset
FeSe

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37Pressure not reportedunknown
LaFeAsO1-xFx

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28Pressure not reportedunknown
BaFe2-xCoxAs2

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22Pressure not reportedunknown
Ba(Fe1-xCox)2As2

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22Pressure not reportedunknown

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