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Inverse Iron Isotope Effect on the Transition Temperature of the (Ba,K)Fe2As2 Superconductor

Parasharam M. Shirage, Kunihiro Kihou, Kiichi Miyazawa, Chul-Ho Lee, Hijiri Kito, Hiroshi Eisaki, Takashi Yanagisawa, Yasumoto Tanaka, Akira Iyo

DOI 10.1103/PhysRevLett.103.257003 · Physical Review Letters

T1

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Abstract

We report that the (Ba,K)Fe2As2 superconductor (transition temperature, Tc∼38 K) has an inverse iron isotope coefficient αFe=−0.18(3) (where Tc∼M−αFe and M is the iron isotope mass); i.e., the sample containing the large iron isotope mass depicts a higher Tc. Systematic inverse shifts in Tc were clearly observed between the samples using three types of Fe isotopes (Fe54, natural Fe, and Fe57). This indicates the first evidence of the inverse isotope effect in high-Tc superconductors. This anomalous mass dependence on Tc implies an exotic coupling mechanism in Fe-based superconductors.

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FormulaReported Tc (K)Pressure (GPa)Type
(Ba,K)Fe2As2

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38Pressure not reportedunknown
(Ba,K)Fe2As2

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38Pressure not reportedunknown
LaFeAsO1-xFx

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26Pressure not reportedunknown
(Ba,K)BiO3

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30Pressure not reportedunknown
MgB2

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40Pressure not reportedunknown
CaC6

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11Pressure not reportedunknown

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