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Importance of structural instability to high-temperature superconductivity

A. Bussmann-Holder, A. Migliori, Z. Fisk, J. L. Sarrao, R. G. Leisure, S.-W. Cheong

DOI 10.1103/PhysRevLett.67.512 · Physical Review Letters

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Abstract

The orthorhombic-tetragonal structural phase transition of La2−xSrxCuO4 is quantitatively analyzed as a function of composition x within an anharmonic electron-phonon interaction model. The correct temperature dependence of the soft mode and the elastic constant c66 is obtained. The double-well potential in the electron-phonon interaction is derived self-consistently and found to vary strongly with x. In the vicinity of the superconducting transition temperature Tc electron–two-phonon interactions dominate the harmonic ones which may explain the high Tc’s observed.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
La2-xSrxCuO4

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—Pressure not reportedunknown
Ba1-xKxBiO3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
BaPb1-xBixO3

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
YBa2Cu3O7

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
La1.85Sr0.15CuO4

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—Pressure not reportedunknown
La1.86Sr0.14CuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown
La1.90Sr0.10CuO4

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—Pressure not reportedunknown
La2-xBaxCuO4

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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