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Effects of substitution of Zn for Cu in the spin-Peierls cuprate, CuGeO3: The suppression of the spin-Peierls transition and the occurrence of a new spin-glass state

M. Hase, I. Terasaki, Y. Sasago, K. Uchinokura, H. Obara

DOI 10.1103/PhysRevLett.71.4059 · Physical Review Letters

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Abstract

The magnetic susceptibilities of polycrystalline Cu1−xZnxGeO3 were measured to study the effects of nonmagnetic impurities on the spin-Peierls transition. The transition temperature drastically reduces upon Zn doping and the spin-Peierls state collapses around x=0.03. The Zn doping causes another phase transition in the samples with 0.02≤x≤0.08, which proved to be spin-glass-like. The present Letter provides the first study of the spin-Peierls system with impurities.

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