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Evidence for Charge Kondo Effect in Superconducting Tl-Doped PbTe

Y. Matsushita, H. Bluhm, T. H. Geballe, I. R. Fisher

DOI 10.1103/PhysRevLett.94.157002 · Physical Review Letters

T1

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Abstract

We report results of low-temperature thermodynamic and transport measurements of Pb1−xTlxTe single crystals for Tl concentrations up to the solubility limit of approximately x=1.5%. For all doped samples, we observe a low-temperature resistivity upturn that scales in magnitude with the Tl concentration. The temperature and field dependence of this upturn are consistent with a charge Kondo effect involving degenerate Tl valence states differing by two electrons, with a characteristic Kondo temperature TK∼6 K. The observation of such an effect supports an electronic pairing mechanism for superconductivity in this material and may account for the anomalously high Tc values.

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FormulaReported Tc (K)Pressure (GPa)Type
Pb1-xTlxTe

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1.5Pressure not reportedmidpoint

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