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Anomalous Fermi-Surface Dependent Pairing in a Self-Doped High-Tc Superconductor

Yulin Chen, Akira Iyo, Wanli Yang, Xingjiang Zhou, Donghui Lu, Hiroshi Eisaki, Thomas P. Devereaux, Zahid Hussain, Z.-X. Shen

DOI 10.1103/PhysRevLett.97.236401 · Physical Review Letters

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Abstract

We report the discovery of a self-doped multilayer high Tc superconductor Ba2Ca3Cu4O8F2 (F0234) which contains distinctly different superconducting gap magnitudes along its two Fermi-surface sheets. While formal valence counting would imply this material to be an undoped insulator, it is a self-doped superconductor with a Tc of 60 K, possessing simultaneously both electron- and hole-doped Fermi-surface sheets. Intriguingly, the Fermi-surface sheet characterized by the much larger gap is the electron-doped one, which has a shape disfavoring two electronic features considered to be important for the pairing mechanism: the van Hove singularity and the antiferromagnetic (π/a, π/a) scattering.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Ba2Ca3Cu4O8F2

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60Pressure not reportedunknown
Ba2Ca3Cu4O8(OδF1-δ)2

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

105Pressure not reportedunknown

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