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Coexistence of multiphase superconductivity and ferromagnetism in lithiated iron selenide hydroxide [(Li1−xFex)OH]FeSe

Christian Urban, Ilya Valmianski, Ursula Pachmayr, Ali C. Basaran, Dirk Johrendt, Ivan K. Schuller

DOI 10.1103/PhysRevB.97.024516 · Physical Review B

T1

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Abstract

We present experimental evidence for (a) multiphase superconductivity and (b) coexistence of magnetism and superconductivity in a single structural phase of lithiated iron selenide hydroxide [(Li1−xFex)OH]FeSe. Magnetic field modulated microwave spectroscopy data confirms superconductivity with at least two distinct transition temperatures attributed to well-defined superconducting phases at TSC1=40±2 K and TSC2=35±2 K. Magnetometry data for the upper critical fields reveal a change in the magnetic order (TM=12 K) below TSC1 and TSC2 that is consistent with ferromagnetism. This occurs because the superconducting coherence length is much smaller than the structural coherence length, allowing for several different electronic and magnetic states on a single crystallite. The results give insight into the physics of complex multinary materials, where several phenomena governed by different characteristic length scales coexist.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
[(Li1-xFex)OH]FeSe

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40Pressure not reportedonset
[(Li1-xFex)OH]FeSe

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

35Pressure not reportedonset
[(Li0.8Fe0.2)OH]FeSe

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

43Pressure not reportedunknown

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