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Evidence for Topologically Protected Surface States and a Superconducting Phase in [Tl4](Tl1−xSnx)Te3Using Photoemission, Specific Heat, and Magnetization Measurements, and Density Functional Theory

K. E. Arpino, D. C. Wallace, Y. F. Nie, T. Birol, P. D. C. King, S. Chatterjee, M. Uchida, S. M. Koohpayeh, J.-J. Wen, K. Page, C. J. Fennie, K. M. Shen, T. M. McQueen

DOI 10.1103/PhysRevLett.112.017002 · Physical Review Letters

T1

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Abstract

We report the discovery of surface states in the perovskite superconductor [Tl4]TlTe3 (Tl5Te3) and its nonsuperconducting tin-doped derivative [Tl4](Tl0.4Sn0.6)Te3 as observed by angle-resolved photoemission spectroscopy. Density functional theory calculations predict that the surface states are protected by a Z2 topology of the bulk band structure. Specific heat and magnetization measurements show that Tl5Te3 has a superconducting volume fraction in excess of 95%. Thus Tl5Te3 is an ideal material in which to study the interplay of bulk band topology and superconductivity.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Tl5Te3

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2.4Pressure not reportedunknown
Tl5Te3

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

2.4Pressure not reportedunknown

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