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An ab Initio Answer to Long-Debated Questions about Superconducting Nb3Sn

Alessio Cucciari, Lilia Boeri

DOI 10.1103/dmwh-1sbf · PRX Energy

T1

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Abstract

Nb3Sn is the workhorse superconductor for high-field applications; however, several fundamental aspects remain open 70 years after its discovery. Using anharmonic ab initio Migdal-Eliashberg theory, we resolve three key questions: (1) the cubic-to-tetragonal martensitic transition is weakly first order; (2) the superconducting gap is strongly anisotropic but continuous over the Fermi surface; and (3) the drop of Hc2 across the transition arises from both reduced electron-phonon coupling and a redistribution of Fermi velocities. The orbital origin of the gap anisotropy suggests targeted doping strategies: Sn-site substitution can increase both Tc and Hc2, while Nb-site substitution raises Hc2 at the cost of lowering Tc.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Nb3Sn

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18.3Pressure not reportedunknown
Nb3Sn

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Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

—Pressure not reportedunknown

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