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Electronic structure of the A15 superconductors Nb3Sb and V3Si

Jianghao Yao, Chunxiang Wu, Tongrui Li, Jianyang Ding, Zhisheng Zhao, Yuzhe Wang, Rui Xu, Zhengtai Liu, Jishan Liu, Mao Ye, Minghu Fang, Donglai Feng, Juan Jiang

DOI 10.1103/k3rt-q85v · Physical Review B

T1

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Abstract

Superconductors with A15 structure have been studied for decades, with recent research focusing on their potential topological band structures and spin Hall effects. However, direct electronic structure studies are still lacking. Here, we have investigated the electronic structure of Nb3Sb and V3Si using angle-resolved photoemission spectroscopy. The band structure reveals pronounced three-dimensional features, which are overall consistent with the results of our density-functional theory calculations. Notably, a band renormalization factor of 1.44 is required for V3Si, whereas no such renormalization is needed for Nb3Sb, indicating stronger correlation effect in V3Si. Flat bands are present in both samples, located at −0.28 eV below the Fermi level in Nb3Sb and nearly touching Fermi level in V3Si, thereby enhancing the density of states near Fermi level and thus responsible for the higher superconducting critical temperature of V3Si. Both Nb3Sb and V3Si feature four- and eightfold degenerate fermions at the R point. Moreover, Nb3Sb is also characterized by a topological invariant of Z2 = 1, confirming it as a strong topological material, which might be responsible for its nonsaturating magnetoresistance. Our results give fundamental understanding of the electronic structure and band topology of the A15 superconductors, fill the long-standing gap of the experimental electronic structure study of these materials.

Source-reported materials — not catalogue approval

FormulaReported Tc (K)Pressure (GPa)Type
Nb3Ge

Archive — visibility unverified

Source-occurrence policy only; no material identity or catalogue acceptance is inferred from the formula.

23.2Pressure not reportedunknown
Nb3Sb

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0.2Pressure not reportedunknown
V3Si

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17.1Pressure not reportedunknown

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